Geodes

A host of different minerals may be found in the interior of some geodes, and when cut open a geode typically makes a beautiful display.

Definition

Geodes are roughly spherically shaped bodies that are lined on the inside with inward-projecting small crystals surrounded by a layer of crystalline quartz. Geodes are most frequently found in limestone beds, but they may also occur in volcanic rocks and in some shales.

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Overview

Typically, a geode consists of a thin outer shell of dense chalcedonic silica (silicon dioxide) and an inner shell of crystals made of quartz or calcite. These crystals are often beautifully terminated, pointing toward the hollow interior. New crystal layers frequently grow on the terminations of old layers, sometimes nearly or even completely filling the geode. Many geodes are filled with water, while others that have been exposed at the surface for some time are dry.

Geodes typically range in size from less than 5 centimeters to more than 30 centimeters in diameter, but they can be much larger. Although the crystals are usually composed of quartz, they may also be composed of carbonate minerals, such as calcite, dolomite, and aragonite; of oxideminerals, such as hematite and magnetite; or of sulfide minerals, such as pyrite, calcopyrite, and sphalerite. In some geodes, there is an alternation of layers of silica and calcite, and almost all geodes show some kind of banding. When sulfide minerals are present, they are often the innermost crystals, whereas the carbonate minerals are typically next to the outermost layer of chalcedony (a fine-grained, fibrous variety of quartz). Some geodes are partially filled by mounds of banded chalcedony in which successive layers differ markedly in color and translucency. These layers form a colorful agate when stained.

The origin of geodes is somewhat similar to the formation of large limestone caves. groundwater dissolves some of the limestone and forms a cavity in the rock, and the cavity is usually left filled with salty water. Silica-bearing waters then coagulate into a gel that surrounds the salt solution. The geode grows by expansion because of osmotic pressure between the salty water trapped inside the silica gel shell and fresh water on the outside of the gel. These pressures cause the geode to expand until equilibrium is reached. Dehydration of the gel and subsequent crystallization occur, along with shrinkage and cracking of the geode wall, allowing mineral-bearing waters to percolate into the geode and deposit crystals on the cavity wall. Subsequent periods of water circulation and crystallization may follow, forming the characteristic layers of crystals.

Geodes are found in many parts of the world. One well-known type found in Uruguay is called hydrolite, or water stone, because it contains quartz crystals left when water containing silica in solution evaporated. Many highly prized geodes that are filled with beautiful crystals and curved-banded colors of agate can be found at various collecting sites in the United States, such as near Dugway, Utah, and Keokuk, Iowa.