Dielectric constant
The dielectric constant is a crucial measurement that quantifies how easily electrical energy can pass through a substance, often compared to its permeability in free space or vacuum. This property is essential for determining whether a material acts as a good conductor or a good insulator. Materials such as glass, plastic, and ceramics exhibit dielectric properties, meaning they do not readily allow electricity to flow through them due to a lack of free electrons. Conversely, substances with high dielectric constants, like metals and salt water, conduct electricity more freely.
Dielectrics play vital roles in applications like capacitors, where they serve as insulators between conductive elements, preventing current flow while storing electrical energy. The dielectric constant can vary across different materials, including solids, gases, and even certain liquids, impacting their suitability for various engineering applications. Additionally, synthetic dielectrics can be engineered to possess specific properties, allowing for customization to meet precise operational needs.
Factors such as temperature, material condition, and surrounding substances can influence the dielectric constant, potentially transforming an insulator into a conductor under certain conditions. Understanding and measuring the dielectric constant is critical not only in scientific research but also in practical manufacturing contexts.
Dielectric constant
A dielectric constant is the measure of the amount of electrical energy that a substance allows to pass through itself. It also may be referred to as the relative permeability of the substance. The dielectric constant is the ratio of the degree to which a substance is permeable to the permeability of free space. All substances, including air, have a dielectric constant. The constant defines whether the substance is a good conductor or a good insulator.
![The dielectric constant. By Lejla peace (Own work) [CC BY-SA 3.0 (http://creativecommons.org/licenses/by-sa/3.0)], via Wikimedia Commons rssalemscience-259282-149129.jpg](https://imageserver.ebscohost.com/img/embimages/ers/sp/embedded/rssalemscience-259282-149129.jpg?ephost1=dGJyMNHX8kSepq84xNvgOLCmsE2epq5Srqa4SK6WxWXS)
![A 1:1 isolation transformer with extra insulation between primary and secondary, usually constructed from a few layers of mylar tape. By Constant314 (Own work) [CC0], via Wikimedia Commons rssalemscience-259282-149130.jpg](https://imageserver.ebscohost.com/img/embimages/ers/sp/embedded/rssalemscience-259282-149130.jpg?ephost1=dGJyMNHX8kSepq84xNvgOLCmsE2epq5Srqa4SK6WxWXS)
Background
The term dielectric originated in correspondence between two English scientists, William Whewell (1794–1866) and Michael Faraday (1791–1867). Whewell is credited with crafting the names of a number of new scientific concepts, including ion and cathode, in response to requests from Faraday. Correspondence between the two men in 1850 records Whewell suggesting the combination of the Greek dia, meaning "through," and the Greek electron, which had already been adopted to name the force known as electricity.
The word dielectric describes a material that does not conduct electricity. This means that the material's natural tendency is not to allow an electrical current to pass through it. Materials such as ceramics, glass, and plastic are considered dielectric because they do not naturally allow electricity to pass through them. Dielectrics make good insulators because they contain, rather than transmit, an electrical field.
This property of dielectrics occurs because of polarization. Polarization is the direction in which the waves of electricity are traveling. Positive charges travel in one direction; negative charges travel in the opposite direction. Dielectric materials such as glass and ceramic naturally have very few free electrons within them that can react to an electrical charge, so the positive and negative charges remain separated, and electricity does not flow. This characteristic of being a poor conductor makes dielectric materials good insulators and containers for electrical current.
While materials such as glass, plastic, and ceramics are among the most commonly known dielectric materials, other non-solid substances have dielectric properties and make good insulators or containment fields for electrical current. These include dry air and gases such as nitrogen and helium. Dry gases can be such good insulators that they are often used in situations where high energy containment is needed, such as radio-frequency transmission lines and high-energy capacitors. A capacitor is an energy storage device that generally includes two conductive elements, such as metal plates that transmit electricity, separated by a dielectric material that does not conduct electricity. Dry gases serve as very efficient dielectrics in capacitors.
Overview
The dielectric constant of a material is the numeric measurement of how easily electricity can permeate, or go through, the substance. This measurement is calculated in comparison to how electricity can move through free space, or a vacuum. Substances with higher dielectric constants conduct electricity easily; most metals and salt water fall into this category. Dry gases have a low dielectric constant; they do not conduct electricity easily. A number of solid substances, such as glass, plastic, ceramics, some forms of water, and mica, have a dielectric constant in the middle range; they are generally not good conductors.
While the dielectric constant is similar to a dipole moment, a key difference exists. Dipole refers to the separation of the negative and positive electrical charges. This is also a factor in dielectric constants; however, a dipole moment is at the molecular level, while a dielectric constant is a macroscopic measurement that is performed using an uncontaminated, pure sample of the material in question.
Determining the dielectric constant of materials is an important factor for many scientific and manufacturing purposes. One key use is in capacitors; engineers need to determine the best materials to store and conduct the electricity (substances with high dielectric constants) and the best substances to contain the current (substances with lower dielectric constants). Different usages have different requirements; for instance, a large capacitor used in a piece of machinery might use a heavy, solid metal to conduct electricity and a ceramic-like substance to contain the electric field. A tiny circuit board, in which size and weight might be critical factors, might need a different type of metal and might use a gaseous substance as the insulator. Knowing the dielectric constant of each material can help engineers make the correct choices.
Most of the time, the materials used as insulators are solids or gases with low to medium dielectric constants. However, some liquids have dielectric constants that allow them to function as insulators. For example, oils such as silicone oil and mineral oil can serve as insulators in transformers.
While in many cases engineers choose existing substances for specific uses based on their dielectric constant, scientists have found ways to manufacture synthetic dielectric substances. Many plastics are used as insulators in part because scientists are able to engineer them to have a specific hardness, resilience, and strength. Through the manipulation of these factors, scientists can customize a substance with the ideal dielectric constant for a particular use. Substances such as polymers, nylon, polystyrenes, polyvinyls, and polycarbonates are often used in places where glass or rubber would have been used in the past.
It is possible for the dielectric constant of a substance to be affected by an extremely large electric charge. Sometimes temperature, the condition of the material, and the type of substances surrounding the material will cause it to begin to breakdown. In this case, the dielectric constant may change a material that was formerly an insulator into a conductor. This generally causes further breakdown and additional changes to the material's dielectric constant.
Bibliography
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