Weight and Mass Measurement

Summary

Mass is an intrinsic property of matter and remains constant regardless of the force of gravity. An object's weight varies according to variation in the force of gravity acting upon it. Both mass and weight are relative quantities rather than absolute. They are fundamental to quantifying human economic and social transactions. The development of standardized systems of weights and measures has been necessary for advancements in science, technology, and commerce. Modern standards of weights and measures include the metric system, or International System of Units (SI), though other systems exist, including the Imperial and US customary systems.

Definition and Basic Principles

It is impossible to state the absolute mass or weight of any material object. At the most fundamental level, one can only state that a hydrogen atom has the mass of a single proton and a single electron. It is impossible to know the absolute masses of those subatomic particles. This basic relationship, however, provides the means by which other atoms can be ascribed to their corresponding masses, and the effects of accumulated mass become observable.

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Weight is the product of an object's mass and the gravitational force acting on that mass. A hydrogen atom that, on Earth, has the mass of one proton plus one electron must, by definition, have the same mass wherever it is located. The gravitational force experienced by that atom will be different in other places. At each location, it will have a different weight while maintaining the same relative mass as other atoms. The same logic applies to larger quantities of matter because of this atomic relationship.

When the gravitational force experienced by different masses is common to their weights, it is expedient, though not absolutely correct, to use the terms mass and weight interchangeably in common usage. To quantify these properties in a meaningful and useful way, it is also necessary to define some standard quantity of each to use as a reference to which other masses and weights can be compared. Devices calibrated to correspond to the standard value can measure other material quantities. International standardization of weights and measures assists trade fairness and facilitates the comprehension of scientific, technological, and theoretical work in disparate locations.

Background and History

In prehistoric times, measured amounts of materials most likely consisted of handfuls and other amounts, with little or no consideration beyond the equivalency of perceived value. There is an intrinsic conflict in this measurement, such as weight versus volume. At some point, it would be realized that a container of large seeds had a sensibly different weight than the container filled with small seeds, arrowheads, fish, or whatever might be traded at the time. The concept of fair exchange on an equivalent weight or equivalent volume basis, or the development of some means of relating weight and volume, would be the beginning of the standardization of weights and measures.

History does not record the beginning of standardization. However, ancient records reveal that certain standard measurements were used in ancient times, such as cubits for distance and talents and carats for weights. Each measurement is related to some basic definition, often merely the distance between two body parts, and it varies from person to person and place to place. Through the sixteenth, seventeenth, and eighteenth centuries, the Imperial or British measurement system was the accepted standard around much of the world. It, and the related US customary system, continues to be used in some places and contexts.

In 1790, a commission of the French Academy of Science developed a standardized system of weights and measures that defined unitary weights, volumes, and distances on quantities that were deemed unchangeable and that related to each other in some basic manner. This metric system has since developed into the Système international d'unités (International System of Units; abbreviated SI) and is the universal standard recognized and used worldwide. Even the Imperial and US systems were redefined regarding the metric system.

How It Works

All weight and mass measurements are relative and cannot be known as absolute values. The definition of standard weights and measures provides a reference framework in which units can be treated as absolute measurements.

For the measurement of mass, the metric standard unit is the kilogram (kg), corresponding to 1,000 grams (g). The gram, in turn, is defined as the mass of 1 cubic centimeter (cm3) of pure water at its temperature of maximum density. Under those conditions, therefore, 1 kg of water occupies a volume of 1,000 cm3, called 1 cubic decimeter (dm3) or 1 liter (l). This is a readily understandable definition, but to have an unchanging standard to which other weights may be readily compared, a solid object is required.

The international prototype standard kilogram is housed at the International Bureau of Weights and Measures in Sèvres, France. It is a small cylinder that is exactly 39 millimeters (mm) in diameter and length, and the alloy is 90 percent platinum and 10 percent iridium. To protect the constant value of its mass and weight, it is stored under inert gas in a specially constructed triple bell jar to protect it from exposure that could affect the object's mass. Over sixty countries worldwide hold registered precise copies of the prototype standard kilogram, similarly protected. These have traditionally been taken by special secure couriers to France through a series of special precautionary procedures, which are then compared with the true prototype kilogram for calibration. Following this procedure, the copies are returned to the appropriate national government, which serves as the legal measurement standard until their next calibration.

Given the security measures for air transportation and international entry, the method has been associated with a very high degree of fallibility. For all but the most legally sensitive of applications, less stringent standards are commonly used. It is sufficient for essentially all purposes that a less precise comparison be used. This permits devices that determine mass and weight to be designed with preset comparisons and arbitrarily adjustable to accepted weight standards. This is typically achieved through the use of standard weight sets that—though neither as stable nor as stringently controlled as the prototype standard—are nevertheless uniformly consistent and conform to the tolerances stated by governing regulations. Typically, these are standardized stainless steel objects or specific electromagnetic conditions known to exert a specific force.

Applications and Products

Because mass is an intrinsic property of matter inextricably tied to weight, its proper measurement is essential in many different fields. The applications and products that have been developed to accommodate the various fields all use the same basic principle of mass comparison, as indeed they must.

Scales and Balances. Scales and balances measure mass or weight. These terms, though often used interchangeably, are technically different. A balance functions by directly comparing the mass to be determined with known masses. The two are deemed equal when a properly constructed balancing scale indicates equality.

The simplest device, called a two-pan beam balance, consists of a crossbeam from which two pans are suspended to hold the masses to be compared. The crossbeam is balanced on a knife-edge fulcrum and attached to a device that indicates deflection from the neutrality point. The unknown mass is placed on one of the pans, and the known masses are placed on the other pan until the scale balances again at the neutrality point. At that point, the unknown mass on one pan is equal to the sum of the known masses on the other pan.

Variations of the pan balance have been constructed and used in mass capacities ranging from grams to several tonnes (1 tonne [t], or metric ton = 1,000 kg). The smallest variations have been used primarily in scientific research involving small quantities of matter, while the largest variations have been used for weighing large quantities of goods for transport.

With the application of electronics, beam balances are replaced by scale balances (commonly just called scales) that do not directly compare masses. Instead, a scale uses the beam balance principle to quantify an unknown mass by comparing it with a calibrated scale against a known force. The amount of deflection of the scale applied by the unknown mass against the known force determines the quantity of the unknown mass. This tends to simplify the procedure by eliminating the requirement to maintain a set of known comparative masses (a set of standard weights) that are always subject to physical damage, chemical attack, and loss. However, it also requires that the functional force and electromagnetic feedback systems be routinely tested and calibrated.

Science and Engineering. Mass and weight are central concepts of science and engineering, especially chemistry and physics. In chemistry, mass is central to all chemical reactions and processes. All masses are relative, beginning with the mass of the hydrogen atom. This provides the basis for assigning a corresponding mass to every other type of atom that can be identified.

Because of this relative relationship, it is possible to relate the number of atoms or molecules in a sample to a weight that can be measured. The number of hydrogen atoms required to make up a bulk mass equal to 1 g must be the same as the number of atoms of carbon (assigned atomic mass = 12) required to make up a bulk mass equal to 12 g, and so on. This equivalency is called the gram-equivalent weight, and the number of atoms or molecules required to make up a gram-equivalent weight is termed 1 mole. Every properly balanced chemical equation specifies the number of moles of each different material in the process, corresponding exactly to the number of atoms or molecules involved in each single instance of the reaction. Without this concept, the science of modern chemistry would not exist. It is worth noting that this concept would not have developed had medieval alchemists not applied the measurement of material weights in their studies.

Physics, in its journey to the present, has been shaped by the concepts of mass and weight. These concepts are not just abstract ideas but practical tools used to measure forces. A force can only be quantified by measuring its effect relative to a mass that has itself been quantified. This is the essence of Newtonian mechanics, where a force is equal to the product of mass and acceleration (F = ma). Newtonian mechanics, however, is not sufficient to describe the small structure of atoms and molecules. This is the realm of quantum mechanics, of which Newtonian mechanics is a subset.

Mass, at the atomic and molecular level, remains critical in scientific analyses, particularly in the analytical procedure called mass spectrometry. In this methodology, the masses of molecular fragments carrying a positive electrical charge are determined by the magnitude of the interaction of that charge with an applied electromagnetic field. Another procedure, called isotopic labeling, is used to measure the effect of atomic mass on the vibrational frequency of specific bonds in spectroscopic analyses and on the rates of reactions in chemical kinetics. These methods, which depend on highly specialized techniques of measuring mass, provide essential information about molecular structures and behaviors, demonstrating the ongoing relevance and importance of mass measurement in scientific analyses.

Social Context and Future Prospects

The world is a material one, and the concepts of mass and weight are inseparable from matter. All aspects of society are impacted by mass and weight in some manner. The single most significant economic expenditure of commerce and society is the energy required for the movement and transportation of mass. This is closely related to other physical aspects, such as tribology, the study of friction and lubrication, and applied physics, the study of the properties and utilization of condensed matter. Tribological effects, all intimately associated with the movement of mass and the corresponding weight, are estimated to carry an immediate economic cost of about 4 percent of a nation's gross national product, with one-third of all energy expenditures made to overcome friction. If the frictional effects involved in transporting mass could be reduced or eliminated, the economic and social benefits would be immense. Even the movement of heating materials, such as natural gas, exacts an economic cost because of that material's mass and weight. Scientists have explored mechanisms of superlubricity, which would greatly reduce friction on an atomic level.

The green movement, which includes energy-efficient building methods, works toward minimizing the economic impact of mass movement. At the same time, it engenders its own costs in that area. Trade and commerce will always demand mass and weight measurement practices and practitioners to maintain stability, productivity, efficiency, and fairness.

To ensure measurement methods remain valid, reliable, and standardized across fields of study, the National Institute of Standards and Technology (NIST), regulated by the Department of Commerce, regularly publishes handbooks outlining changes and updates relating to measurement.

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