Electrospinning

Electrospinning is a method for making extremely thin fibers called nanofibers. Nanofibers are used in the manufacture of a variety of products used for the consumer, scientific, and health-care markets. The electrospinning process applies an electrical current to materials such as polymers, ceramics, or composites, depending on the final use of the nanofiber. The process is a simple and cost-effective way to make these fibers, which are increasingly important for a wide range of applications.

Background

Nanofibers are very fine thread-like structures with a diameter of 100 nanometers or less. A nanometer is a measurement corresponding to a billionth of a meter. Nanofibers can be made by many different processes, including drawing, thermal-induced phase separation, and electrospinning.

Scientists have known about the basic process behind electrospinning since the end of the nineteenth century. However, it was not until the second half of the twentieth century that interest in developing the technique grew. British physicist Sir Geoffrey Ingram Taylor is credited with expanding the study of the cone-shaped flow of fluid that is crucial to the electrospinning process.

In the early 1960s, Taylor observed that this cone has specific properties, such as each spot on the cone having the same potential as every other spot, something physicists refer to as an equipotential surface. Taylor also determined that the cone continually exists in steady equilibrium, where all the forces that are exerted against the substance in the cone are balanced against each other. His work was so important to the process that this cone is now known as the Taylor cone in his honor.

Overview

An electrospinning device has three main parts. These include a reservoir for holding the material to be spun, a high-voltage electrical supply, and something to collect the fiber as it is spun. In addition, the process requires a substance to be spun into the nanofiber.

The reservoir is often similar to a syringe with a very fine needle. The needle or the end of the reservoir must be made of metal and must also be sufficient in size to hold the type of material to be spun. This material is often a polymer. A polymer is a substance made up of many long, repeating chains of molecules. Molecules are two or more atoms held together by chemical bonds that have a neutral electrical charge. Polymers can either be natural—such as water and wood—or synthetic. Plastics, polyester, and epoxies are examples of synthetic polymers. These are very commonly used in electrospinning nanofibers. However, nanofibers can also be spun from ceramics and composite substances.

The substance to be spun is loaded into the reservoir or syringe. The tip of the reservoir where the substance is loaded is then exposed to a high-voltage electrical charge. This charge can range from 5 to 50 kilovolts (kV). The solution is pushed through the reservoir at a consistent rate. This causes the substance to exit the thin metal end of the reservoir in a Taylor cone.

As the substance leaves the reservoir, it moves towards a collection device. This device is made of metal and is usually grounded and electrically neutral. The collection device can be a sheet, plate, mesh, or some other form of metal that will gather the material. The substance in the reservoir is pushed out at a consistent rate through the electrically charged end of the reservoir. This causes the substance to be stretched into a stream of charged material that is attracted to the collection device. In the process, it is turned into a nanofiber.

By manipulating the variables in the electrospinning process, different types of nanofibers can be created. One of the most significant variables will be the substance being spun. Substances differ in how well they conduct or resist electricity. This will change how the electrospinning process is set up and affect the final product. The type of material and its viscosity—a measure of how thick or watery the substance is—will be determined by the type of nanofiber that is produced.

A number of other factors can also help make fibers of different thickness, form, and consistence. For example, the entire electrospinning device can be mounted vertically or horizontally. This will affect the rate and angle at which the charged substance moves towards the collection device. The electrical charge can be increased or decreased. The collection device can be stationary or rotating, and can be closer or farther from the syringe releasing the substance. The pressure applied as the solution is pushed through the reservoir can be increased or decreased. In addition, room conditions such as temperature and humidity will also impact how the substance is formed into fibers.

By manipulating the type of substance and the many variables in the process, the completed nanofibers can be made to meet different specifications. They can be straight and aligned with each other, like straight hair or animal fur. They can also be bent and twisted into a more random pattern, like a tangle of yarn. The finished fibers can be made thicker or thinner, depending on their final usage.

Electrospinning is important because it is a simple, flexible, productive, and cost-effective way to create large amounts of nanofibers with many different properties. Nanofibers have become increasingly important in twenty-first century nanotechnology. Nanotechnology and nanofibers are used in many different industries and applications. For example, they are an important part of healthcare where they can be used to help absorb toxins in the blood and to isolate cancer cells. Nanofibers can also serve as a scaffold or framework for organic tissue to help regenerate damaged cartilage or skin. They are also used in electronics, consumer goods, and in many other ways.

Bibliography

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Malara, Angela. "Environmental Concerns on the Use of the Electrospinning Technique for the Production of Polymeric Micro/Nanofibers." Scientific Reports, 9 Apr. 2024, www.nature.com/articles/s41598-024-58936-5. Accessed 21 Nov. 2024.

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